


Exposure to Heat
The decomposition the hydrogen peroxide is exothermic and likewise the rate of decomposition boosts with enhancing temperature. If the warmth of decomposition is not gotten rid of at the price at which the is occurred (by heat loss come the next site or cooling), the temperature will rise and the rate of decomposition will increase. This event can an outcome in a self-accelerating decomposition which, in the situation of badly contaminated solutions, may finish in exceptionally rapid decomposition or “boil off”.
Venting and Circulation
For solutions up come 64% concentration liquid water is quiet present, even after the full decomposition. because of this, the final decomposition temperature can not exceed the boiling allude of water. for solutions higher than 64% concentration, adequate heat is created to evaporate all of the water. Super-heated solution has actually potential to reason container rupture. Example, 70% hydrogen peroxide can reach a temperature that 240°C (513 K). One volume of 70% solution, when totally decomposed under adiabatic conditions and atmospheric pressure, will certainly produce around 2,500 volumes of gas compared to the original volume.You are watching: Why is hydrogen peroxide stored in a dark bottle
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Storage Container Materials
