You are watching: Which alcohol reacts most rapidly with the lucas reagent?
The use of thionyl chloride because that converting alcohols to alkyl chlorides has the included benefit that both of the by-products, sulfur dioxide and hydrogen chloride, space gases. This characteristic simplifies the isolation and purification that the reaction product.
In the laboratory, one have the right to test for the presence of alcohols through Lucas reagent (a mixture of concentrated hydrochloric acid and zinc chloride). Lucas reagent counter alcohols come alkyl chlorides: tertiary alcohols give an immediate reaction, indicated when the alcohol systems turns cloudy; second alcohols usually show evidence of reaction within 5 minutes; main alcohols execute not reaction to any far-ranging extent. Thus, Lucas reagent can assist distinguish amongst primary, second and tertiary alcohols.
This page looks at reaction in i beg your pardon the -OH group in one alcohol is replaced by a halogen such together chlorine or bromine. It consists of a simple test for an -OH group using phosphorus(V) chloride. The general reaction looks like this:
< ROH + HX ightarrow RX + H_2O >
Reaction through hydrogen chloride
Tertiary alcohols react reasonably promptly with concentrated hydrochloric acid, yet for main or an additional alcohols the reaction prices are too sluggish for the reaction to be of much importance. A tertiary alcohol reaction if that is shaken v with focused hydrochloric acid at room temperature. A tertiary halogenoalkane (haloalkane or alkyl halide) is formed.
Scope the ReactionThe bespeak of reactivity the alcohols is 3° > 2° > 1° methyl.The stimulate of reactivity that the hydrogen halides is hello > HBr > HCl (HF is usually unreactive).
The reaction is acid catalyzed. Alcohols react with the strongly acidic hydrogen halides HCl, HBr, and HI, however they perform not react with nonacidic NaCl, NaBr, or NaI. Major and an additional alcohols have the right to be convert to alkyl chlorides and also bromides by allowing them come react v a mixture of a salt halide and also sulfuric acid:
Reacting Alcohols v Phosphorus Halides
Alcohols react with liquid phosphorus(III) chloride (also dubbed phosphorus trichloride) to yield chloroalkanes.
< 3CH_3CH_2CH_2OH + PCl_3 ightarrow 3CH_3CH_2CH_2Cl + H_3PO_3 label1.1.3a>
Alcohols additionally violently react through solid phosphorus(V) chloride (phosphorus pentachloride) in ~ room temperature, producing clouds of hydrogen chloride gas. While the is not a great approach to make chloroalkanes, that is a great test for the visibility of -OH groups. To display that a substance to be an alcohol, you would first have to get rid of all the other groups that likewise react v phosphorus(V) chloride. Because that example, carboxylic acids (containing the -COOH group) likewise react with it (because the the -OH in -COOH) as does water (H-OH).
If you have a neutral liquid not contaminated v water, and also clouds of hydrogen chloride are produced when you include phosphorus(V) chloride, climate you have an alcohol group present.
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< CH_3CH_2CH_2OH + PCl_5 ightarrow CH_3CH_2CH_2Cl + POCl_3 + HCl label1.1.4>
There are likewise side reactions including the (POCl_3) reacting v the alcohol.