Main distinction – Gravimetric vs Volumetric Analysis

The quantity of a constituent present in a mixture of constituents deserve to be established using either gravimetric evaluation or volumetric analysis. This methods deserve to be supplied to determine the purity that a ingredient in a provided sample. The main difference between gravimetric and volumetric evaluation is that in gravimetric analysis, the massive of the analyte is determined whereas, in volumetric analysis, the volume of the analyte is determined.

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Key locations Covered

1. What is Gravimetric Analysis – Definition, Process, needs 2. What is Volumetric Analysis – Definition, Titration as a Volumetric Analysis method 3. What is the Difference between Gravimetric and also Volumetric Analysis – to compare of key Differences

Key Terms: Buchner Funnel, Filtration, Gravimetric Analysis, Mass, Titration, Volatilization, Volumetric Analysis


What is Gravimetric Analysis

Gravimetric evaluation is a procedure of measure up the amount of an analyte by its mass. Hence, that is a quantitative determination. Here, the desired constituent in a liquid is convert to a solid kind that can quickly be separated and weighed in stimulate to recognize the lot of it and also that heavy mass have the right to be used for further analysis. The usual gravimetric evaluation will have the following steps.

Preparation that a solutionSeparation the the wanted constituent native the solutionWeighing the lot of constituent

In stimulate to do this analysis a success, the constituent must be totally precipitated as a pure compound and also it also must be basic to different the precipitate via filtration. Because that the development of a precipitate, a reagent is included to the solution. This reagent is recognized as a precipitating agent. One of two people a filtration technique or a volatilization technique can be used to separate the precipitate from the solution,


Figure 1: An analytical balance, which can be used to get an exact weight because that a very tiny amount the sample obtained via precipitation.

Here, filtration includes filtering of the fluid phase, leave the hard precipitate top top the filter paper. The separation the the precipitate deserve to be done using the adhering to methods;

Filtration under gravityFiltration in a Buchner funnel (vacuum filtration)Volatilization of the fluid phase leaving the precipitate

Some applications of gravimetric analysis include precipitation the Ag+, Pb+2, and Hg22+ together halides, precipitation of Ca2+ as calcium oxalate (CaC2O4), precipitation of Ba2+ together Barium sulfate (BaSO4), etc.

What is Volumetric Analysis

Volumetric analysis is a process used to determine the amount of the wanted constituent through its volume. Therefore it is a quantitative determination. Here, the volume the the constituent is measure via a titration (titrimetric analysis).

In titrations, a reagent that deserve to react through the analyte is added as proportions till all analyte molecule react v the reagent molecules. Once both the sample and the reagent space colorless solutions, one indicator have to be provided in order to identify the endpoint of the reaction. The endpoint indicates the end of the analyte molecules.


Figure 2: Apparatus because that Titration

The indicator is a reagent that can provide a color adjust when the endpoint has actually been reached. The color readjust occurs when a change in the reaction mixture has actually occurred. Because that example, an acid-base indicator is sensitive to the adjust of pH in the reaction mixture. It offers the color change when the pH is changed. But some reagents act as self-indicators. Ex: Potassium permanganate.

The reagent supplied to recognize the quantity of analyte should completely and quickly react v all analyte molecules. The concentration that this reagent have to be known and also the portions added should it is in noted, because these details are compelled for the calculate of the concentration that the analyte.

Difference in between Gravimetric and Volumetric Analysis


Gravimetric Analysis:  Gravimetric analysis is a procedure of measure the lot of one analyte by its mass.

Volumetric Analysis: Volumetric evaluation is a procedure used to identify the amount of a wanted constituent by its volume.

Parameter Determined

Gravimetric Analysis:  In gravimetric analysis, the fixed of the analyte is determined.

Volumetric Analysis: In volumetric analysis, the volume the the analyte is determined.


Gravimetric Analysis: Gravimetric analysis involves the formation of a hard mass known as a precipitate, which deserve to be separated from the sample solution.

Volumetric Analysis:  Volumetric analysis is done via a titration, in which the volume that analyte is identified by including portions the a reagent (of known concentration) that can react v the analyte.


Gravimetric Analysis: Gravimetric evaluation generally gives the final result in grams – g (sometimes in milligrams – mg).

Volumetric Analysis: Volumetric analysis gives the final an outcome in milliliters –mL (sometimes in microliters – μm).


Gravimetric and volumetric evaluation techniques room two types of analytical approaches that are used to measure up the quantity of a certain constituent existing in a provided sample. The key difference between gravimetric and also volumetric analysis is that in gravimetric analysis, the fixed of the analyte is figured out whereas, in volumetric analysis, the volume the the analyte is determined.

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1. “Volumetric Analysis.” , easily accessible here.2. “Gravimetric analysis.” Encyclopædia Britannica, Encyclopædia Britannica, inc., 9 Mar. 2016, obtainable here.3. “Wired Chemist.” Volumetric Analysis, obtainable here.

Image Courtesy:

1. “Analytical balance mettler ae-260” By us DEA -(Public Domain) via Commons Wikimedia2. “Acid and Base Titration” by Kengksn – Own job-related (CC BY-SA 4.0) via Commons Wikimedia