Carbon tetrafluoride is colorless and also odorless gas through the chemistry formula CF4. It is non-flammable gas and is used as a refrigerant in various industries. That is an extremely stable as result of the strength of that carbon-fluorine bond. 

In this article, us will discuss Carbon tetrafluoride (CF4) lewis dot structure, its molecular geometry, is the polar or non-polar, link angle, hybridization, etc. 

CF4 is slightly dissolve in water but miscible with miscellaneous organic solvents. A high concentration that this gas can reason a deficiency of it is provided of air come the body which leader to abnormal breathing. This problem is well-known as asphyxiation.

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Properties the Carbon tetrafluoride

It can come to be a drug at high temperatures.It is nonflammable and also soluble in chloroform and benzene.It is a potent greenhouse gas.It has a molar massive of 88.0043 g/mol.It has a boiling allude of −127.8 °C and a melting allude of −183.6 °C.
Name the MoleculeCarbon tetrafluoride
Chemical formulaCF4
Molecular geometry that CF4Tetrahedral
Electron geometry the CF4Tetrahedral
Bond angle109.5º
Total Valence electron for CF432
The formal charge of CF40

Page Contents display
1 exactly how to draw lewis structure for CF4 (Carbon tetrafluoride)
2 follow some procedures for drawing the lewis dot framework of CF4
3 What space the electron and also molecular geometry of CF4?
4 follow some procedures to uncover CF4 molecule geometry
5 Carbon tetrafluoride polarity: is CF4 polar or nonpolar
6 Three factors that show the polarity that CF4
7 What is the formal fee in CF4 lewis structure and how to calculation it?
9 an overview

How to attract lewis structure for CF4 (Carbon tetrafluoride)

CF4 lewis structure consists of one carbon and four fluorine atom, carbon is in the center, and all fluorine atoms neighboring it. No lone pair current on the central atom of the CF4 lewis period structure yet 3 lone pairs current on each outer atom.

The lewis diagram of CF4 is very similar to CCl4. Stop see step by step how to draw this in a very simple way with every explanations.

Follow some procedures for illustration the lewis dot framework of CF4

1. Count full valence electron in CF4

The electrons uncovered in the outermost covering of one atom are dubbed valence electrons. To uncover the valence electrons in the CF4 molecule, look in ~ the periodic team of every atom existing in it. Together carbon is positioned in the 14th group and fluorine in the 17th. Therefore, the valence electron present in carbon is 4 and also for fluorine, the is 7.

Now to find valence electrons in the CF4 molecule, simply add the carbon and also fluorine valence electrons.

⇒ total valence electron in Carbon = 4

⇒ complete valence electron in Fluorine = 7

∴ full valence electron available for drawing the CF4 lewis structure = 4 + 7*4 = 32 electrons <∴CF4 has 4 fluorine atom>


2. Discover the the very least electronegative atom and also placed it at center

Here we require to find the the very least electronegative atom in the CF4 molecule so the we deserve to place it at the facility in the lewis diagram. Electronegativity constantly increases native left to ideal in the periodic table. But we recognize fluorine is the many electronegative element in chemistry. So, fluorine constantly goes exterior in lewis’s diagram.

Hence placed carbon in ~ the center in the lewis diagram and fluorine spaced evenly approximately it.


3. Connect outer atom to central atom through a solitary bond

Now we have actually to connect each outer atom come the central atom with a solitary bond come initiate the lewis framework of CF4. So, attach all fluorine atom to the carbon atoms with the assist of a solitary bond.


As you view in the above structure, we associated all fluorine atoms to the carbon atoms through the assist of 4 single bonds. And every single bond has actually 2 electrons in it.

Therefore, 4 single bonds typical 8 electron we provided in the over structure indigenous the complete of 32 valence electrons easily accessible for illustration the CF4 lewis dot structure.

∴ (32 – 8) = 24 valence electrons.

Now, the remaining valence electron we have actually are 24.

4. Ar remaining valence electrons beginning from outer atom first

In this step, we must put the remaining valence electrons around the outer atom very first to finish their octet. So, in a CF4 molecule, the outer atom is fluorine and also fluorine needs 8 electron in that is valence covering to complete its octet.

So, start placing the staying valence electrons roughly fluorine atoms an initial to finish their octet.


Lewis dot structure of CF4

As you check out in the above CF4 lewis period structure, we put 6 electrons roughly each fluorine atom because fluorine currently sharing the 2 electrons v the aid of a solitary bond current in between carbon and also fluorine. So, each fluorine has actually 8 electrons about them and also that is sufficient for completing your octet.

Now, carbon which is the main atom also needs 8 electron in that valence shell to perfect the octet rule. However by looking at the over structure, we come to know carbon currently sharing 8 electrons v the aid of 4 solitary bonds attach to fluorine atoms.

So, both atom (Carbon and fluorine) of the CF4 molecule finish their octet comfortably.

Hence, we got our stable Carbon tetrafluoride lewis structure.

According come the VSEPR theory, any kind of molecule the has four bonded atoms linked with a main atom and also no lone pair present on the central atom repurchase the tetrahedral geometry. In the case of CF4, every fluorine atoms space attached come a carbon atom, and no lone pair is present on the central atom. So, the molecular geometry of CF4 is tetrahedral.

Also, all fluorine atom bonded come carbon atom lie at the corners of the tetrahedron with a 109.5º bond angle in between them. 

The electron geometry that CF4 is additionally tetrahedral.

Let’s see exactly how to uncover the electron and also molecular geometry the the CF4 molecule:-

Follow some steps to discover CF4 molecule geometry

1. Uncover the number of lone pairs existing on the main atom of the CF4 lewis dot structure 

The lone pair is non-bonding electrons the don’t take component in chemical bonding. Together per the CF4 lewis structure, no lone pair is present on the main atom (carbon). 

Or girlfriend can check the lone pair on the main atom by the formula provided below-


So, carbon is the central atom the is enclosed to 4 fluorine atoms v the aid of a solitary bond and it has 4 valence electrons in that outermost shell.

So, L.P. Top top carbon = (4 – 4)/2

= 0

∴ The lone pair on the central atom of the CF4 molecule is 0.

2. Find hybridization number of CF4

“Hybridization is the ide of mixing atomic orbitals into new hybrid orbitals (with various energies, shapes, etc., climate the component atom orbitals) suitable for the pairing of electron to kind chemical bonds in valence bond theory”.

To uncover the hybridization of one atom we need to look at its hybridization number or steric number.

Use the given formula to discover the hybridization number for CF4.

Hybridization variety of CF4 = (Number of atom attached to Carbon + Lone pair ~ above Carbon)

As every the CF4 lewis structure, carbon has 4 atoms(fluorine) attached come it and also no lone pair existing on it.

So, Hybridization number = 4 + 0 

= 4

So, the hybridization number for CF4 is 4 which means it has actually Sp³ hybridization.

Hybridization numberHybridization

3. Use VSEPR theory or AXN method to determine CF4 molecular geometry

“The form of a molecule counts upon the variety of valence shell electron pairs around the central atom.”

According come Valence covering electron pair repulsion theory if the molecule central atom has actually zero lone pair and sp³ hybridization climate the molecular geometry of that molecule will certainly be tetrahedral.


Molecular geometry that CF4

Now usage another technique to uncover the molecule geometry the CF4. AXN method


As every CF4 lewis structure, AXN notation of it follow as-

A = Carbon is a central atom.X = four fluorine atoms attached to the carbon.N = No lone pair present on the carbon atom.

So, the share formula because that CF4 is AX4.

According come the VSEPR chart, if the molecule has AX4 share formula then the molecule shape and electron geometry of the molecule will certainly be tetrahedral.

Bonded atomsLone pairGeneric formulaHybridizationMolecular geometryElectron geometry
30AX3Sp²Trigonal planarTrigonal planar
21AX2NSp²BentTrigonal planar
12AXN2Sp²LinearTrigonal planar
31AX3N1Sp³Trigonal pyramidTetrahedral
32AX3N2Sp³dT-shapedTrigonal bipyramidal
51AX5NSp³d²Square pyramidal


Is CF4 polar or non-polar? The CF4 molecule is nonpolar because of its symmetry tetrahedral structure however the bond existing in it polar.

The tetrahedral geometry results in a symmetrical arrangement of polar bonds approximately the carbon atom, together a result, the same charges are spread within the molecule which helps to cancel the end the shortcut dipole. The network dipole moment of CF4 is zero.

Let’s take review of the important determinants for determining the polarity the CF4.

Three components that suggest the polarity of CF4

1. Electronegativity: 

Higher the electronegativity of one atom much more is the power of attracting electrons in the direction of itself. The electronegativity because that fluorine is 3.98 and also for carbon, it is 2.5. These electronegativity difference between the carbon and fluorine atom provides each bond polar(C-F).

Each separation, personal, instance C-F polar link can quickly be canceled out because of the symmetry tetrahedral shape of the CF4 molecule.

2. Dipole moment

The network dipole minute of CF4 is zero. Together the fluorine is more electronegative 보다 carbon. So, that attracts an ext electrons towards itself, i beg your pardon generates an electrical dipole represented as a vector, direction indigenous carbon come the fluorine atom.

More electronegative atoms create a partial an unfavorable charge on the whereas various other ones generate a confident charge on it. This separation of optimistic and negative charges is measure up by dipole moment.

The vector sum of these 4 individuals bond(C-F) dipole is zero because all fluorine atoms room pulling electrons from carbon is in an equal and opposite direction.

So, every C-F polar binding canceled out leaving this molecule together nonpolar in nature.

3. Geometrical or molecular shape

The molecular geometry that CF4 is tetrahedral through all exact same atoms in the surrounding. “If all four surrounding atoms space the exact same in a tetrahedral, climate the molecule will always be nonpolar. The only exception is if because that some factor one or much more of the bordering atoms had actually a lone pair.”

As the tetrahedral form of the CF4 molecule results in the direction of the dipole moment of everyone bond being opposite to the vector sum of the other three dipoles. Hence, they will cancel out each other and also generate zero dipole minute in the molecule.

What is the formal charge in CF4 lewis structure and how to calculate it?

The formal fee of CF4 shows that i beg your pardon atom(carbon or fluorine) has a more positive or negative charge present on it. 

To calculation the formal charge in CF4 lewis period structure. Usage this equation provided below:

⇒ Formal charge = (Valence electrons – unbonded electron – 1/2 bonded electrons)

Now we will certainly calculate the formal fee on carbon i beg your pardon is the main atom in the CF4 lewis structure.

⇒ Valence electron of carbon = 4

⇒ Non-bonding (lone pair) electrons on carbon = 0

⇒ Bonding electron attached come carbon = 8 <∴ 4 single bonds that contain 8 electrons>

∴ (4 – 0 – 8/2)

= 0 is the formal fee on carbon in the CF4 molecule.

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How numerous bonded pairs and also lone bag of electrons present in the CF4 lewis structure?

According come the CF4 lewis dot structure, the bonded pair of electrons in CF4 is 8(4 single bonds) and the lone pair of electrons is 24(3 lone bag on every fluorine atom). 

Are the lewis structure and molecular geometry the CF4 is very same as CCl4?

Yes, the molecule geometry and lewis structure of CF4 is the same as CCl4 because of the very same generic formula(AX4) because that both of them.